Histry Chem

Knowledge

Phenyl Salicylate Material Safety Data Sheet (MSDS)

Identification

Product Name: Phenyl Salicylate
Synonyms: Salol
Chemical Formula: C13H10O3
Molecular Weight: 214.22 g/mol
CAS Number: 118-55-8
Recommended Use: Laboratory chemicals, pharmaceutical applications, industrial synthesis
Manufacturer: Contact information as listed on supplier documentation
Emergency Phone Number: Refer to national poison center or supplier support line

Hazard Identification

Classification: Not classified as a hazardous substance under GHS criteria, though caution should always follow lab practice
Hazard Statements: May cause eye, skin, and respiratory irritation
Signal Word: None
Pictograms: None for GHS, though wear PPE as a safeguard
Precautionary Statements: Avoid contact with eyes, skin, and clothing. Use only in well-ventilated areas. Prevent particulate dispersal
Other Hazards: Combustible in finely divided form. Dust may cause mechanical irritation

Composition / Information on Ingredients

Chemical Identity: Phenyl Salicylate
Common Name: Salol
Concentration: 100% pure (unless otherwise specified by supplier)
CAS Number: 118-55-8
EC Number: 204-258-7
Impurities: Not anticipated in analytical-grade or industrial product, purity documented in supplier analysis

First Aid Measures

Inhalation: Remove person to fresh air. Restore breathing if necessary. Medical attention for persistent symptoms
Skin Contact: Wash affected area thoroughly with soap and water. Remove soiled clothing and launder before reuse
Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Seek medical help if irritation develops
Ingestion: Rinse mouth, do not induce vomiting. Water may be given if victim is alert. Immediate medical attention advised for significant exposure
Most Severe Symptoms: Irritation, coughing, redness, stomach discomfort

Fire-Fighting Measures

Suitable Extinguishing Media: Use carbon dioxide, dry chemical powder, alcohol-resistant foam, or water spray
Unsuitable Media: Direct stream of water may spread material
Specific Hazards: Burning produces irritating and toxic fumes including carbon monoxide and carbon dioxide
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective clothing. Move containers from fire area if possible
Special Procedures: Cool containers with water spray to prevent rupture due to heat. Avoid inhaling combustion products

Accidental Release Measures

Personal Precautions: Wear protective equipment as outlined in Exposure Controls/Personal Protection. Avoid dust formation or inhalation
Environmental Precautions: Prevent spill from entering drains, sewers, or bodies of water
Methods for Cleanup: Sweep up and collect into suitable containers for disposal. Clean remains with damp cloths or mop and properly ventilate area
Additional Measures: Notify appropriate authorities if large spill occurs. Dispose based on local, regional, and national regulations

Handling and Storage

Safe Handling: Use in ventilated spaces. Avoid creating dust. Wear gloves and safety glasses. Do not eat, drink, or smoke while handling
Storage Conditions: Store in a tightly closed container in a cool, dry, well-ventilated area away from incompatible substances such as strong oxidizers
Storage Temperature: Room temperature is generally suitable, avoid heat sources
Secondary Containment: Recommended for larger quantities
Incompatibilities: Oxidizing agents, strong acids, strong bases

Exposure Controls and Personal Protection

Exposure Limits: No established OSHA, NIOSH, or ACGIH exposure limits as of latest available information
Engineering Controls: Use local exhaust ventilation or work with material in a fume hood to reduce airborne exposure
Protective Equipment: Appropriate gloves (nitrile or equivalent), safety goggles, lab coat recommended
Respiratory Protection: Dust mask or respirator if ventilation is inadequate or dust generation likely
Hygiene Measures: Wash hands thoroughly after use and before breaks. Remove contaminated clothing and clean before reuse

Physical and Chemical Properties

Appearance: White to off-white crystalline powder
Odor: Slightly sweet, faint odor
Odor Threshold: Not determined
pH: No data
Melting Point/Freezing Point: 41-43°C (105-110°F)
Boiling Point: 305°C
Flash Point: >150°C (closed cup)
Evaporation Rate: Not available
Flammability: May be combustible in finely divided form
Vapor Pressure: Negligible at room temperature
Vapor Density: Not established
Relative Density: About 1.24 g/cm³
Solubility: Slightly soluble in water, soluble in alcohols, ethers, and benzene
Partition Coefficient (n-octanol/water): log Kow ~3.2
Auto-Ignition Temperature: Not available
Decomposition Temperature: Not clearly established
Viscosity: Solid at room temperature

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions
Reactivity: No significant reactivity hazards
Possibility of Hazardous Reactions: May react with strong oxidizers
Conditions to Avoid: Excessive heat, open flames, dust formation
Incompatible Materials: Strong oxidizing agents, strong acids, strong bases
Decomposition Products: Carbon monoxide, carbon dioxide, and possibly irritating organic fumes on burning

Toxicological Information

Acute Toxicity: LD50 (oral, rat): approx. 3100 mg/kg
Routes of Exposure: Inhalation, skin contact, eye contact, ingestion
Symptoms of Exposure: Irritation to eyes, skin, and upper respiratory tract; stomach upset if swallowed in significant amount
Carcinogenicity: Not listed by IARC or NTP as a carcinogen
Chronic Effects: Prolonged or repeated exposure may cause skin dryness or cracking
Sensitization: No known reports
Mutagenicity: No conclusive data
Reproductive Toxicity: No evidence identified in accessible studies

Ecological Information

Aquatic Toxicity: Expected to have low acute toxicity to aquatic organisms
Persistence and Degradability: Can be biodegradable, but specific rate not well established
Bioaccumulation Potential: Moderate potential based on octanol-water partition coefficient
Mobility in Soil: Low water solubility limits migration
Other Adverse Effects: No noted significant effects on wildlife at normal environmental concentrations

Disposal Considerations

Waste Treatment Methods: Dispose in accordance with local, regional, and national laws. Generally, chemical incineration or landfilling in approved facility
Container Disposal: Thoroughly clean before disposal or offer recycling where possible
Avoid Release: Prevent uncontrolled disposal to soil, drains, or streams
Special Instructions: Consult waste authorities for detailed guidance

Transport Information

UN Number: Not classified as hazardous for transport
UN Proper Shipping Name: Non-regulated chemical
Transport Hazard Class: Not dangerous according to road, rail, sea, or air transport regulations
Packing Group: Not assigned
Environmental Hazards: Not regarded as dangerous to the environment
Special Precautions: Basic chemical hygiene. Keep packages dry and well-sealed

Regulatory Information

Inventory Status: Listed in TSCA (United States), EINECS (Europe), DSL (Canada), and other international chemical inventories
Regulations: No specific OSHA, SARA, or RCRA controls for phenyl salicylate alone, but standard chemical hazard communication rules apply
Labeling Requirements: As per OSHA Hazard Communication Standard, appropriate hazards must be communicated
Right-to-Know Laws: Product details disclosed according to national and regional right-to-know requirements
Other Regulations: Users should check additional national, regional, or local regulations concerning chemical safety