Product Name: Hexyl Salicylate
Chemical Formula: C13H18O3
CAS Number: 6259-76-3
Synonyms: 2-Hydroxybenzoic acid hexyl ester; Salicylic acid hexyl ester
Recommended Use: Fragrance ingredient, flavoring agent in cosmetics and personal care products
Supplier Information: Name, address, and emergency contact of the responsible manufacturer
GHS Classification: Eye irritation (Category 2A), Skin irritation (Category 2)
Label Elements: Signal word - Warning; pictogram - exclamation mark
Hazard Statements: Causes skin irritation, causes serious eye irritation
Precautionary Statements: Wear protective gloves and eye protection, avoid breathing vapors, wash hands thoroughly after handling
Potential Health Effects: May cause skin or respiratory tract irritation; prolonged exposure may increase risk
Chemical Name: Hexyl Salicylate
CAS Number: 6259-76-3
Concentration: More than 94% by weight
Impurities: May contain trace amounts of salicylic acid and other related esters
Inhalation: Move affected person to fresh air, keep comfortable, seek medical attention if symptoms develop
Skin Contact: Remove contaminated clothing, rinse skin with plenty of water, seek medical advice if irritation persists
Eye Contact: Rinse with water for at least 15 minutes, lift eyelids occasionally, seek immediate medical attention
Ingestion: Rinse mouth thoroughly, do not induce vomiting, obtain medical assistance right away
Symptoms: Redness, burning sensation, tearing, coughing, sore throat
Suitable Extinguishing Media: Dry chemical, foam, carbon dioxide, water spray
Unsuitable Extinguishing Media: Direct water jets
Fire Hazards: Flammable vapors may form in heated tanks or containers, can produce toxic fumes (CO and CO2) when burning
Protective Equipment: Firefighters wear self-contained breathing apparatus and protective clothing
Specific Hazards: Vapors may travel along ground and ignite at distant points, closed containers may rupture due to pressure build-up when exposed to extreme heat
Personal Protection: Use chemical-resistant gloves, protective goggles, and clothing, avoid breathing vapors
Environmental Precautions: Prevent further leakage or spillage if safe, keep out of sewers, drains, and waterways
Clean-Up Methods: Contain spillage, absorb with inert material (sand, earth, or vermiculite), transfer to labeled container for disposal, ventilate area
Additional Guidance: Wash contaminated area with soap and water, collect contaminated cleaning agents for disposal
Handling: Use local or general exhaust ventilation, avoid contact with skin and eyes, never eat, drink, or smoke while handling chemical, wash hands and exposed areas after use
Storage: Store in a cool, dry, well-ventilated place, keep container tightly closed and safe from incompatible materials (strong oxidants, acids, bases), keep away from sources of ignition
Incompatibles: Keep away from strong oxidizers, acids, and alkalis, avoid excessive heat and sunlight
Engineering Controls: Use in well-ventilated areas, preferably under a chemical hood
Exposure Limits: No established OSHA, ACGIH, or NIOSH occupational exposure limits
Engineering Controls: Provide sufficient mechanical or local exhaust to control airborne levels below nuisance thresholds
Personal Protection: Chemical-resistant gloves made of nitrile or neoprene, safety glasses with side-shields or chemical splash goggles, protective clothing, appropriate respirator if ventilation is inadequate
Hygiene: Always wash hands after handling, remove and wash contaminated clothing before reuse, eye wash fountains and emergency showers recommended
Appearance: Clear colorless to pale yellow liquid
Odor: Sweet, floral, slightly herbal
Boiling Point: About 282 °C (539.6 °F)
Melting Point: Less than -20 °C
Flash Point: Approximately 137 °C (278.6 °F) (closed cup method)
Vapor Pressure: Very low at room temperature
Solubility: Insoluble in water, miscible with typical organic solvents
Density: 1.03 g/cm³ at 20 °C
Viscosity: Moderate
Chemical Stability: Stable under normal handling and storage conditions, degrades under strong heat or sunlight
Hazardous Reactions: Contact with oxidizing agents may cause a vigorous reaction, can develop peroxides upon long-term storage
Conditions to Avoid: High temperatures, open flames, strong light, incompatible chemicals
Decomposition Products: Thermal breakdown may release toxic smoke containing carbon monoxide, carbon dioxide, and other organics
Polymerization: Not expected under standard conditions
Likely Routes of Exposure: Skin, eyes, inhalation, ingestion
Acute Toxicity: LD50 (oral, rat) > 5,000 mg/kg; considered to have low acute toxicity
Skin Sensitization: Skin may become irritated or inflamed after repeated or prolonged contact
Eye Effects: May cause moderate to severe irritation
Inhalation: High vapor concentrations can irritate respiratory tract
Chronic Exposure: No clear evidence of long-term effects from repeated low-level exposures in animals or humans
Carcinogenicity: Not listed as a carcinogen by NTP, IARC, OSHA
Eco-toxicity: Harmful to aquatic organisms, may cause long-term effects in the aquatic environment
Mobility: Low water solubility limits environmental mobility; adsorbs to soil and sediment
Biodegradability: Expected to be at least partially biodegradable in aerobic conditions
Bioaccumulation: Potential exists due to lipophilicity, risk of accumulation in food chains
Other Adverse Effects: No significant risk of ozone depletion or global warming potential documented
Waste Treatment: Dispose of chemical and contaminated packaging in accordance with national and local regulations, do not pour into drains or waterways
Methods: Incineration preferred for large waste, small amounts can be absorbed in a non-combustible absorbent and placed in chemical waste container for lawful disposal
Precautions: Wear suitable protective equipment to avoid contact with waste streams
Recommendations: Consult local hazardous waste disposal authority for approval and details
UN Number: Not regulated under most modes as a hazardous material
Proper Shipping Name: Hexyl Salicylate
Transport Hazard Class: Non-hazardous under ADR, IMDG, IATA
Packing Group: Not applicable
Labeling: No transport pictograms required, maintain proper packaging to prevent leaking
Special Precautions: Secure containers during transit to avoid breakage or spills
Inventory Status: Listed in TSCA (USA), REACH (EU), DSL (Canada)
Safety Assessment: IFRA standards and local cosmetic regulations may limit allowable concentrations for finished products
Hazard Communication: Subject to workplace communication standards via SDS and labeling
Reporting Requirements: No specific EPA, SARA, or CERCLA reportable quantity for this compound
Other Regulations: Suitable for uses approved by national authorities, always follow site-specific chemical hygiene plans
