Histry Chem

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Material Safety Data Sheets (MSDS) of Bio-Based Solvents

d-Limonene

Identification: d-Limonene
Hazard Identification: Causes skin irritation, may cause allergic skin reaction, flammable liquid, harmful to aquatic life with long lasting effects.
Composition / Information on Ingredients: d-Limonene 97-100% (CAS No. 5989-27-5)
First Aid Measures: If inhaled, move to fresh air. Skin contact: Wash with soap and water. Eye contact: Rinse with plenty of water, remove contact lenses. Ingestion: Rinse mouth, do not induce vomiting.
Fire-Fighting Measures: Use dry chemical, foam, or CO2. Wear full protective gear including a self-contained breathing apparatus because vapors can ignite.
Accidental Release Measures: Eliminate ignition sources, ventilate area, use absorbent materials like sand. Avoid runoff into drains or waterways.
Handling and Storage: Store away from antioxidant chemicals, in a cool, ventilated place. Keep container tightly closed.
Exposure Controls and Personal Protection: Use safety glasses, gloves and protective clothing. Work in well-ventilated areas.
Physical and Chemical Properties: Colorless to pale yellow liquid, citrus odor, boiling point 175°C, flash point 48°C.
Stability and Reactivity: Stable under recommended storage, can react with acids and strong oxidizers.
Toxicological Information: May irritate skin, eyes, respiratory system; oral LD50 (rat) >5 g/kg.
Ecological Information: Toxic to aquatic organisms, may cause long-term adverse effects.
Disposal Considerations: Dispose according to local, state, and federal regulations. Do not pour into drains.
Transport Information: UN2319, Flammable Liquid, PG III
Regulatory Information: SARA Title III, TSCA Inventory, listed on EINECS.

Ethyl Lactate

Identification: Ethyl Lactate
Hazard Identification: Flammable liquid and vapor, causes serious eye irritation, may cause skin irritation.
Composition / Information on Ingredients: Ethyl Lactate >98% (CAS No. 97-64-3)
First Aid Measures: Eyes: Rinse thoroughly with water for several minutes. Skin: Wash off with soap, remove contaminated clothing. Inhalation: Move to fresh air. Ingestion: Rinse mouth, seek medical attention if unwell.
Fire-Fighting Measures: Use water spray, dry powder, or CO2. Firefighters wear self-contained breathing apparatus and full gear.
Accidental Release Measures: Remove ignition sources, ventilate area, collect spillage in inert absorbent. Avoid entry into waterways.
Handling and Storage: Store in tightly closed container in cool, ventilated place. Keep away from open flames.
Exposure Controls and Personal Protection: Provide local exhaust ventilation. Wear protective gloves, safety glasses, normal work clothing.
Physical and Chemical Properties: Clear, colorless liquid, mild odor, boiling point 154°C, flash point 46°C.
Stability and Reactivity: Stable under normal conditions, avoid strong oxidizers and acids.
Toxicological Information: May cause eye and skin irritation, oral LD50 (rat): 5,870 mg/kg.
Ecological Information: Readily biodegradable, low aquatic toxicity.
Disposal Considerations: Incinerate in compliance with local regulations.
Transport Information: Not regulated under DOT unless in large quantities.
Regulatory Information: TSCA Inventory, REACH registered.

Methyl Soyate

Identification: Methyl Soyate
Hazard Identification: Not classified as hazardous under GHS; may cause mild skin or eye irritation.
Composition / Information on Ingredients: Methyl esters of soybean oil (CAS No. 67784-80-9), 100%.
First Aid Measures: Eyes: Flush with water. Skin: Wash with soap. Inhalation: Move to fresh air. Ingestion: Do not induce vomiting, seek medical help if feeling unwell.
Fire-Fighting Measures: Use water spray, foam, dry chemical or CO2. Wear suitable breathing equipment.
Accidental Release Measures: Stop leak if safe, use absorbent, collect for disposal. Clean with water and detergent.
Handling and Storage: Store in tightly closed containers, away from direct sunlight and excessive heat.
Exposure Controls and Personal Protection: No special ventilation needed for normal use. Wear gloves as good practice.
Physical and Chemical Properties: Pale yellow liquid, faint odor, boiling point >200°C, flash point >150°C.
Stability and Reactivity: Chemically stable, avoid strong acids and bases.
Toxicological Information: Low oral toxicity; may cause mild eye or skin effects.
Ecological Information: Biodegradable, low aquatic toxicity.
Disposal Considerations: Collect and dispose in accordance with local rules.
Transport Information: Not regulated.
Regulatory Information: Listed on TSCA, meets EPA requirements for bio-based content.

n-Butyl Lactate

Identification: n-Butyl Lactate
Hazard Identification: Flammable, causes skin and serious eye irritation, may be harmful if inhaled.
Composition / Information on Ingredients: n-Butyl Lactate (CAS No. 138-22-7), concentration >99%.
First Aid Measures: Eyes: Rinse with water, get medical attention. Skin: Remove contaminated clothing, rinse skin. Inhalation: Remove to fresh air. Ingestion: Rinse mouth, do not induce vomiting.
Fire-Fighting Measures: Extinguish with foam, dry powder or carbon dioxide. Firefighters use full protective clothing.
Accidental Release Measures: Remove ignition sources, ventilate, soak up with inert absorbent.
Handling and Storage: Keep away from sparks and heat, store in ventilated space.
Exposure Controls and Personal Protection: Use chemical goggles and gloves, ensure adequate ventilation.
Physical and Chemical Properties: Colorless liquid, mild odor, boiling point 186°C, flash point 72°C.
Stability and Reactivity: Stable in normal conditions, avoid strong oxidizers.
Toxicological Information: Skin/eye irritant, low acute toxicity (LD50 oral rat 5,000 mg/kg).
Ecological Information: Readily biodegradable, low aquatic toxicity risk.
Disposal Considerations: Incinerate or dispose of according to local/national laws.
Transport Information: Not restricted.
Regulatory Information: TSCA, EINECS listed.

Pine Oil

Identification: Pine Oil
Hazard Identification: May cause skin and eye irritation, flammable, vapor may form explosive mixtures.
Composition / Information on Ingredients: Terpenes (alpha-terpineol, beta-pinene), 100%.
First Aid Measures: Eye contact: Flush with water. Skin: Wash with soap. Inhalation: Move to fresh air. Ingestion: Do not induce vomiting.
Fire-Fighting Measures: Use water spray, foam, CO2, or dry chemical; firefighters wear self-contained breathing apparatus.
Accidental Release Measures: Remove all ignition sources, ventilate, use absorbent.
Handling and Storage: Store in cool, ventilated areas away from oxidizers.
Exposure Controls and Personal Protection: Wear gloves and eye protection; provide local exhaust.
Physical and Chemical Properties: Clear to pale amber liquid, boiling point >200°C, flash point 65°C.
Stability and Reactivity: Stable, avoid oxidizing conditions.
Toxicological Information: LD50 (oral, rat): 3,200 mg/kg. Prolonged exposure may irritate skin.
Ecological Information: Harmful to aquatic life, partially biodegradable.
Disposal Considerations: Dispose as hazardous waste.
Transport Information: Not regulated unless bulk volume.
Regulatory Information: TSCA listed, OSHA regulated.

Furfuryl Alcohol

Identification: Furfuryl Alcohol
Hazard Identification: Harmful in contact with skin or if inhaled, causes skin and eye irritation, combustible.
Composition / Information on Ingredients: Furfuryl Alcohol (CAS No. 98-00-0), >98%.
First Aid Measures: Skin: Remove contaminated clothing, wash with soap. Eyes: Rinse with water, get medical help. Inhalation: Fresh air, possible oxygen aid. Ingestion: Rinse mouth, get immediate medical help.
Fire-Fighting Measures: Use dry chemical, CO2, foam, or water spray. Wear protective gear.
Accidental Release Measures: Prevent entry into drains, ventilate area, use absorbent materials.
Handling and Storage: Store in cool, well-ventilated place, tightly sealed.
Exposure Controls and Personal Protection: Local exhaust, chemical goggles and gloves recommended.
Physical and Chemical Properties: Colorless to light yellow liquid, almond odor, boiling point 171°C, flash point 65°C.
Stability and Reactivity: Unstable with strong acids or bases.
Toxicological Information: Acute toxicity LD50 (oral, rat): 65 mg/kg. Potential respiratory irritant.
Ecological Information: Moderate aquatic toxicity, biodegradable.
Disposal Considerations: Dispose at licensed facility.
Transport Information: UN2874, Packing Group III.
Regulatory Information: SARA, TSCA, OSHA covered.

Sorbitol-Based Solvents

Identification: Sorbitol-Based Solvent
Hazard Identification: Essentially non-hazardous, possible mild irritation to eyes or skin.
Composition / Information on Ingredients: Sorbitol, water, stabilizers as needed.
First Aid Measures: Wash exposed area with water. For eyes, flush thoroughly. Drink water if ingested.
Fire-Fighting Measures: Use appropriate methods for surrounding materials; sorbitol is non-flammable.
Accidental Release Measures: Mop up and wash small spills. Avoid slippery floors.
Handling and Storage: Store at ambient temperature, avoid freezing.
Exposure Controls and Personal Protection: No special equipment for small batch use; for larger operations, wear gloves.
Physical and Chemical Properties: Clear viscous liquid, sweet odor. Boiling point >200°C.
Stability and Reactivity: Stable and non-reactive.
Toxicological Information: Low toxicity; LD50 (oral, rat): 15,900 mg/kg.
Ecological Information: Fully biodegradable.
Disposal Considerations: Rinse with water, dispose in accordance with local rules.
Transport Information: Not regulated.
Regulatory Information: Approved as food additive, TSCA exempt.