Product Name: Benzyl Salicylate
Chemical Formula: C14H12O3
CAS Number: 118-58-1
Synonyms: Benzoic acid, 2-hydroxy-, phenylmethyl ester; Benzyl 2-hydroxybenzoate
Intended Use: Fragrance ingredient in cosmetics, soaps, personal care, industrial fragrance applications
Manufacturer: Supplied by global chemical manufacturers for commercial and laboratory use
Emergency Contact: National Poison Center and manufacturer emergency response numbers set by regional law
Classification: Eye Irritant Category 2, Skin Sensitizer Category 1
Label Elements: Warning symbol (exclamation mark), Signal word: Warning
Hazard Statements: Causes serious eye irritation, may cause allergic skin reaction, potentially harmful to aquatic life
Precautionary Statements: Prompt washing of skin after handling, avoid eye contact, use protective gloves and goggles, prevent release into waterways
Pictogram: Exclamation mark for health hazard, Environmental hazard symbol for aquatic toxicity
Routes of Exposure: Eyes, Skin, Ingestion, Inhalation
Chemical Identity: Benzyl Salicylate
Concentration: 98-100% pure
Impurities: Trace phenol derivatives, minor residual solvents from synthesis
Additives: None identified in standard grade
General Advice: Remove affected individual from exposure. Seek medical help if symptoms persist.
Eye Contact: Rinse eyes with water for at least 15 minutes, lifting eyelids occasionally. Continue flushing and seek medical assistance.
Skin Contact: Remove contaminated clothing, wash skin with plenty of soap and water for at least 15 minutes.
Ingestion: Rinse mouth, do not induce vomiting. Get medical attention if discomfort or symptoms develop.
Inhalation: Move to fresh air, call a doctor if there is difficulty breathing or irritation.
Important Symptoms: Redness, burning, itching of skin or eyes, gastrointestinal effects if swallowed
Suitable Extinguishing Media: Foam, dry chemical, CO2, water spray
Fire Hazards: May emit toxic vapors such as carbon monoxide, carbon dioxide when burning
Protection for Firefighters: Wear positive-pressure self-contained breathing apparatus and protective clothing
Unusual Combustion Products: Dense smoke, aromatic fumes
Special Precautions: Avoid inhaling smoke, keep containers cool with water spray to prevent rupture
Flash Point: 163°C (325.4°F)
Personal Precautions: Evacuate area if release is large, ensure adequate ventilation, avoid all sources of ignition
Protective Equipment: Impermeable gloves, safety goggles, chemical-resistant apron
Environmental Precautions: Contain spill, avoid discharge into drains, waterways, ground.
Cleanup Methods: Absorb liquid spill with inert material (sand, vermiculite), sweep up and place in chemical waste containers, decontaminate area with detergent and water, ventilate space after cleanup is complete.
Disposal: Dispose of collected material in accordance with local hazardous waste regulations to limit contamination
Handling Procedures: Use only in well-ventilated areas to avoid vapor buildup, avoid breathing mist or vapor, avoid contact with skin and eyes by wearing protective gear, maintain clean surfaces
Storage Requirements: Keep tightly closed in original container, store in cool, dry place away from direct sunlight and sources of heat or ignition, segregate from incompatible substances such as strong oxidizers and acids
Packaging Materials: High-density polyethylene, glass, or stainless steel preferred
Special Handling Guidance: Ground and bond containers when transferring product to prevent static discharge, maintain chemical inventories and labeling in accordance with regulation
Occupational Exposure Limits: None established by OSHA, NIOSH, or ACGIH
Engineering Controls: Operate in chemical fume hood or mechanical exhaust, provide eyewash stations and emergency showers in work areas
Personal Protection: Chemical-resistant gloves (nitrile or neoprene), splash proof goggles, lab apron, in case of large splashes use chemical suit
Respiratory Protection: Use local exhaust ventilation, if vapor concentration exceeds safe working levels, use NIOSH-approved respirator
Hygiene Measures: Do not eat, drink, or smoke while handling material, wash hands and face after handling, launder work clothing regularly
Appearance: Clear colorless to pale yellow liquid or crystalline solid
Odor: Slightly sweet, floral, mild aromatic
Molecular Weight: 228.24 g/mol
Melting Point: 24–27°C (75–80°F)
Boiling Point: 320°C (608°F)
Density: 1.17 g/cm3 at 20°C
Solubility: Insoluble in water, soluble in ethanol, diethyl ether, most organic solvents
Vapor Pressure: 1 mmHg at 108°C
pH: Not applicable (neutral ester)
Chemical Stability: Stable under standard conditions of temperature and pressure
Reactivity: Not readily reactive under recommended storage and handling conditions
Incompatible Materials: Avoid strong oxidizers, strong acids, alkalis, halogens
Hazardous Decomposition: Thermal breakdown may produce carbon monoxide, carbon dioxide, irritating aromatic fumes
Polymerization: Does not undergo hazardous polymerization
Special Cautions: Prolonged exposure to heat may degrade product or create pressure buildup in sealed containers
Acute Toxicity: Oral LD50 (rat) >2000 mg/kg
Skin Corrosion/Irritation: Mild to moderate skin sensitizer, possible allergic contact dermatitis from repeated exposure
Eye Damage: Causes moderate eye irritation, tearing, redness
Inhalation Effects: Vapors may cause respiratory irritation, headache, nausea at elevated concentrations
Chronic Effects: Not classified as carcinogen, mutagen, or reproductive toxin by IARC, NTP, OSHA, or EPA
Other Risks: Individual cases of allergic reactions or photosensitivity in prolonged skin contact
Aquatic Toxicity: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Persistence / Degradability: Biodegradable under environmental conditions, though breakdown may generate toxic metabolites
Bioaccumulative Potential: Potential to bioaccumulate in aquatic species considered low due to metabolic breakdown
Mobility in Soil: Limited by insolubility in water; adheres to soil and sediments
Other Environmental Concerns: Larger scale industrial releases contribute to chemical loads in wastewater and effluent; regulatory controls reduce risks of chronic ecological impact
Disposal Methods: Treat as hazardous chemical waste, use certified disposal contractors, avoid landfill disposal, incinerate with appropriate emissions controls
Container Disposal: Triple rinse, puncture and render unusable, follow regional chemical waste programs
Precautions: Never discharge to drains, watercourses, or environment, prevent large releases from entering sewer systems
UN Number: Not classified as hazardous for transport under UN Recommendations
Transport Hazard Class: Not regulated as dangerous goods for road (ADR/RID), air (ICAO/IATA), or sea (IMO/IMDG)
Packing Group: Not assigned
Proper Shipping Name: Benzyl Salicylate
Special Precautions: Protect packaging from damage, leaks, and overheating during transport, label containers clearly
TSCA (USA): Listed
REACH (EU): Registered substance, subject to safety evaluation in consumer products
DSL/NDSL (Canada): Listed
AICS (Australia): Listed
EINECS (Europe): 204-262-9
Labeling Requirements: Comply with requirements for skin sensitizers and aquatic toxicity, include correct pictograms and hazard info on containers
Other Regulatory Info: Cosmetic and fragrance use subject to review by IFRA, regulatory bodies recommend restricted concentration in consumer products based on updated safety data
