Histry Chem

Knowledge

MSDS – 1-Nonanol

Identification

Product Name: 1-Nonanol
Synonyms: Nonyl alcohol, n-nonanol, normal-nonyl alcohol
Chemical Formula: C9H20O
CAS Number: 143-08-8
EC Number: 205-582-1
Recommended Use: Used in fragrances, flavorings, solvents, plasticizers, lubricants, surfactants
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Hazard Identification

Classification: Flammable liquid (Category 3), Irritant (Category 2), Skin irritant (Category 2), Eye irritant (Category 2A)
Signal Word: Warning
Hazard Statements: Causes skin irritation, causes serious eye irritation, may cause respiratory irritation, harmful if swallowed
Precautionary Statements: Keep away from heat, sparks, open flames; avoid breathing vapors; use in well-ventilated areas; wear protective gloves, eye protection
Hazard Symbols: Exclamation mark, flame
Routes of Exposure: Skin, eyes, inhalation, ingestion
Target Organs: Skin, eyes, respiratory tract
Potential Health Effects: Redness, itching, burning in case of contact; coughing and throat irritation from inhaling vapors; abdominal pain and nausea if ingested

Composition / Information on Ingredients

Chemical Name: 1-Nonanol
Concentration: >98%
CAS Number: 143-08-8
Impurities: Trace amounts of homologous alcohols and water (typically below 2%)
Additives: No intentional additives or stabilizers reported

First Aid Measures

Inhalation: Remove to fresh air, keep person at rest, seek medical attention if symptoms continue
Skin Contact: Remove contaminated clothing; wash skin with soap and plenty of water; seek medical attention if irritation develops
Eye Contact: Flush eyes thoroughly with plenty of water for at least 15 minutes, lifting eyelids; obtain medical attention
Ingestion: Rinse mouth with water, do not induce vomiting, get medical advice immediately
Symptoms: Burning sensation, redness, coughing, shortness of breath, abdominal upset
Self-Protection for First Aiders: Avoid direct contact, use gloves and eye protection, ensure sufficient ventilation

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical powder, foam, carbon dioxide, alcohol-resistant foam
Unsuitable Extinguishing Media: Strong water jets
Special Hazards: Vapors can form explosive mixtures with air, thermal decomposition releases toxic fumes (carbon monoxide, carbon dioxide)
Protective Equipment: Firefighters need self-contained breathing apparatus, protective clothing
Firefighting Instructions: Stay upwind, keep containers cool by spraying with water, remove sources of ignition, prevent fire-fighting runoff from entering drains or watercourses

Accidental Release Measures

Personal Precautions: Evacuate area, ventilate space, eliminate ignition sources, avoid contact with skin and eyes
Personal Protection: Wear gloves, protective footwear, safety goggles; use respirator with organic vapor cartridge when adequate ventilation is not possible
Environmental Precautions: Prevent entry into sewers, surface and groundwater systems; notify authorities if large spills occur
Cleanup Methods: Absorb with inert material (sand, vermiculite), collect spill residue in suitable container for disposal, clean contaminated area with soap and water
Disposal: Dispose of spilled material as chemical waste according to local and national regulations

Handling and Storage

Handling: Handle in well-ventilated areas, keep away from flames, hot surfaces, sparks, avoid inhaling vapors and contact with skin and eyes, avoid eating, drinking, or smoking where the product is used
Storage Conditions: Store tightly closed at ambient temperature, in a dry, cool, and well-ventilated location; keep in original container, away from incompatible materials (strong oxidizers, acids), protect from direct sunlight and static discharge
Packing Materials: Use containers made of stainless steel or high-density polyethylene, tightly sealed, labeled appropriately
Storage Class: Flammable liquids

Exposure Controls and Personal Protection

Occupational Exposure Limits: No OSHA PEL or ACGIH TLV set; employers usually keep airborne concentrations low as a matter of best practice
Engineering Controls: Use local exhaust ventilation, process enclosure, safety showers, and eyewash stations in the area
Personal Protection: Nitrile or neoprene gloves, chemical safety goggles or full face shield, flame-resistant clothing, apron, closed footwear
Respiratory Protection: Use air-purifying respirator with organic vapor cartridge when ventilation is insufficient
Hygiene Measures: Wash hands after handling, remove contaminated clothing and wash before reuse, keep food and beverages away from work area

Physical and Chemical Properties

Appearance: Colorless oily liquid
Odor: Pleasant, floral odor
Odor Threshold: 0.2–2 mg/m³ (subjective)
pH: Not applicable (neutral substance)
Melting Point: -6 °C
Boiling Point: 214–216 °C
Flash Point: 94–96 °C (closed cup)
Evaporation Rate: Slower than water
Flammability: Flammable liquid
Upper/Lower Flammability Limits: 0.8%–6.3% (v/v in air)
Vapor Pressure: 0.11 mmHg at 25 °C
Vapor Density: 4.5 (air = 1)
Relative Density: 0.826–0.830 g/cm³ at 20 °C
Solubility: Slightly soluble in water (1 g/L at 25 °C), miscible with ethanol, ether
Partition Coefficient: log Kow 3.4–3.9
Decomposition Temperature: Decomposes above 300 °C
Viscosity: 10.5 cP at 20 °C

Stability and Reactivity

Chemical Stability: Stable under normal handling, storage and usage conditions
Reactivity: Limited reactivity, forms esters easily with acids
Conditions to Avoid: Heat, sparks, open flames, electrostatic discharge, strong sunlight
Incompatible Materials: Strong acids, strong oxidizing agents like peroxides, nitric acid, chlorine
Hazardous Decomposition Products: Carbon dioxide, carbon monoxide, irritating fumes
Hazardous Polymerization: Not reported to occur

Toxicological Information

Acute Toxicity: Oral LD50 (rat): 3200 mg/kg; Dermal LD50 (rabbit): >2000 mg/kg; inhalation toxicity data limited
Corrosivity & Irritation: Skin and eyes show irritation on prolonged exposure
Sensitization: Not regarded as a sensitizer based on available data
Chronic Effects: Extended or repeated exposure may cause defatting of skin, dermatitis
Carcinogenicity: Not listed as carcinogenic in IARC, NTP, OSHA
Mutagenicity: No data indicating mutagenicity
Target Organ Toxicity: Respiratory system and skin upon frequent exposure
Routes of Exposure: May enter body via ingestion, inhalation, skin and eye contact

Ecological Information

Aquatic Toxicity: Fish LC50 (96h): 10–100 mg/L, Daphnia EC50 (48h): 31 mg/L, considered harmful to aquatic life
Persistence and Degradability: Readily biodegradable by microorganisms in soil and water
Bioaccumulative Potential: Moderate (log Kow: 3.4–3.9 indicates some potential for bioaccumulation)
Mobility in Soil: Low to moderate mobility, possible leaching to groundwater
Other Adverse Effects: No data on ozone depletion, global warming or photochemical ozone creation potential; avoid environmental release
Regulation: Subject to aquatic toxicity limitations in some countries

Disposal Considerations

Waste Disposal: Collect and deliver waste to certified hazardous waste processor; do not dispose of product or contaminated packaging down the drain; dilute residues with plenty of water before neutralization if allowed by regulations
Packaging Disposal: Rinse empty containers, recycle or puncture and dispose of according to local requirements; render containers unusable before disposal
Legal Requirements: Classify and handle as hazardous waste; disposal must comply with local, regional, and national environmental regulations
Special Precautions: Avoid release to the environment, seek advice from certified disposal facilities where doubt exists

Transport Information

UN Number: 1993 (Flammable Liquids, n.o.s.)
Proper Shipping Name: Flammable liquid, n.o.s. (contains 1-Nonanol)
Hazard Class: 3 (Flammable liquid)
Packing Group: III
Label: Flammable liquid
Transport Labels: 3 (flame symbol)
IMDG Code: Page 3372; EmS F-E, S-E
Special Provisions: Avoid transport with foodstuffs, reduce vibration and mechanical shocks
Environmental Hazards: Not identified as a marine pollutant
Bulk Transport: Refer to IMO/IMDG, IATA, ADR standards

Regulatory Information

Classification and Labeling: Classified under GHS criteria as hazardous; requires labeling for acute toxicity and flammable liquid
OSHA: Regulated as hazardous under OSHA Hazard Communication Standard
TSCA: Listed on the United States Toxic Substances Control Act inventory
EINECS/ELINCS: Included in European inventory of existing chemical substances
REACH Registration: Registered under EU REACH regulations
SARA Title III: No extremely hazardous substances present above reporting criteria
Proposition 65: Not listed by California Proposition 65
National Chemical Inventories: Listed on AICS (Australia), DSL (Canada), ENCS (Japan), KECI (Korea), PICCS (Philippines), IECSC (China)
Restrictions: Subject to chemical hazard classification, labeling, and worker protection standards in many regions
Country-Specific Requirements: Users must reference applicable local legislation, as safety, environmental, and transport rules may differ