Histry Chem

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1-Chlorotetradecane Material Safety Data Sheet (MSDS)

Identification

Product Name: 1-Chlorotetradecane
Chemical Name: 1-Chlorotetradecane
Synonyms: Tetradecyl chloride, n-Tetradecyl chloride
Chemical Family: Alkyl halide
CAS Number: 4860-03-1
EC Number: 225-606-8
Molecular Formula: C14H29Cl
Molecular Weight: 232.84 g/mol
Recommended Use: Chemical synthesis, intermediate, surfactant production
Supplier: Chemical manufacturers or laboratories specializing in specialty organics
Contact Information: Typical emergency hotlines or poison control (refer to actual supplier data for specifics)

Hazard Identification

GHS Classification: Skin Irritant (Category 2), Eye Irritant (Category 2A), Acute Aquatic Toxicity (Category 3)
Signal Word: Warning
Hazard Statements: May cause skin and eye irritation, harmful to aquatic life with long-lasting effects
Physical State: Oily liquid, faint fragrance
NFPA Rating: Health 2, Flammability 1, Reactivity 0
Pictograms: Exclamation mark, Environmental hazard
Routes of Exposure: Inhalation, skin contact, eye contact, ingestion
Symptoms: Redness, itching, possible burning sensation, gastro-intestinal discomfort if swallowed
Precautionary Statements: Avoid breathing vapors or mist; use gloves, protective goggles, and ventilated spaces; avoid release to the environment

Composition / Information on Ingredients

Chemical: 1-Chlorotetradecane
Purity: ≥98%
Impurities: Long-chain hydrocarbons (<2%), trace polychlorinated by-products
CAS Number: 4860-03-1
Other Components: No additives, no known stabilizers present

First Aid Measures

Inhalation: Move to fresh air, support breathing if unwell, seek medical attention for persistent irritation
Skin Contact: Remove contaminated clothing, thoroughly wash affected skin with mild soap and water, seek medical care if irritation persists
Eye Contact: Rinse eyes carefully with lukewarm water for at least 15 minutes, keep eyelids open, seek medical attention for continued discomfort
Ingestion: Do not attempt to induce vomiting, rinse mouth, give water, seek immediate medical attention
Most Important Symptoms: Moderate redness, irritation, possible abdominal pain on ingestion, dizziness after inhalation
Medical Attention: Treat symptomatically, monitor respiratory and central nervous systems, wash out eyes and skin on continued irritation

Fire-Fighting Measures

Suitable Extinguishing Media: Carbon dioxide, dry chemical powder, foam, water spray (not stream)
Unsuitable Media: Do not use direct water jet as it may spread product
Hazardous Combustion Products: Hydrogen chloride gas, carbon monoxide, carbon dioxide
Specific Hazards: May form toxic gases in fire scenarios, product floats and can re-ignite on water surface
Special Protective Equipment for Firefighters: Wear self-contained breathing apparatus and full protective gear
General Advice: Prevent run-off from entering drains, use water spray to cool unopened containers near fire

Accidental Release Measures

Personal Precautions: Use impervious gloves, chemical-resistant clothing, safety goggles, ensure adequate ventilation
Environmental Precautions: Prevent leakages from entering soil, groundwater, drains, or open water
Methods for Containment: Absorb spills using sand, earth, or inert material, collect in appropriate waste containers
Cleanup Procedures: Wipe contaminated area with detergent and water, dispose of all cleaning materials in accordance with local regulations
Evacuation: Restrict unnecessary personnel, ventilate area well to reduce vapors

Handling and Storage

Handling: Wear proper PPE, avoid inhaling vapors or contact with skin and eyes, use in well-ventilated space, never eat, drink, or smoke while using
Storage Conditions: Store in tightly sealed containers, away from heat, sparks, or open flames, in a cool, dry, and well-ventilated area
Incompatible Materials: Strong oxidizing agents, acids, and alkalis
Safe Packaging: Use containers compatible with alkyl chlorides, clearly label to avoid misuse
Special Requirements: Ground and bond containers when transferring product, segregate from food and feedstuffs

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established ACGIH or OSHA exposure limits for 1-Chlorotetradecane
Engineering Controls: Local exhaust ventilation, use chemical fume hoods for high-volume tasks
Personal Protective Equipment: Chemical-resistant gloves (nitrile, neoprene), splash-proof goggles or face shield, long-sleeved clothing or lab coat, impermeable apron when handling large amounts
Respiratory Protection: Use NIOSH/MSHA-approved respirators for excessive vapor conditions
Hygiene Measures: Wash hands after handling, remove contaminated clothes before breaks

Physical and Chemical Properties

Appearance: Clear, oily liquid
Odor: Mild, hydrocarbon-like
pH: Not applicable
Melting Point: -7 °C
Boiling Point: 310 - 315 °C
Flash Point: 121 °C (250 °F)
Vapor Pressure: Very low at ambient temperatures
Density: 0.85 g/cm³ at 20 °C
Solubility: Insoluble in water, soluble in organic solvents like ether and chloroform
Partition Coefficient (log Kow): Estimated 7.2
Viscosity: Moderate to high
Evaporation Rate: Slow
Decomposition Temperature: Not determined

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions
Possible Hazardous Reactions: May react strongly with strong oxidizers, may generate hydrochloric acid fumes on hydrolysis
Incompatible Materials: Strong acids, alkalis, oxidizing materials
Hazardous Decomposition Products: Hydrogen chloride, carbon oxides under fire conditions
Polymerization: Product does not tend to polymerize

Toxicological Information

Acute Toxicity: Oral LD50 (rat): >5000 mg/kg (practically non-toxic), Inhalation LC50 not available, Skin LD50 (rabbit): >2000 mg/kg
Skin Corrosion/Irritation: Mild to moderate irritant on contact
Serious Eye Damage/Irritation: Causes moderate eye irritation
Respiratory or Skin Sensitization: Not sensitizing based on structure, but repeated exposure may cause dermatitis
Chronic Effects: No data for carcinogenicity, mutagenicity, or reproductive toxicity; repeated exposure may dry skin
Symptoms on Exposure: Redness, soreness, mild chemical burns possible on prolonged or repeated exposure
Medical Conditions Aggravated: Pre-existing skin or respiratory disorders could worsen with exposure

Ecological Information

Aquatic Toxicity: Harmful to aquatic organisms, may cause long-term adverse effects in aquatic environments
Persistence and Degradability: Not rapidly biodegradable, can persist in soil or sediment
Bioaccumulation: High potential; log Kow value above 7 indicates significant accumulation in organisms
Mobility in Soil: Low, product tends to adsorb to soil particles and is not expected to migrate quickly
Other Adverse Effects: May impact aquatic life due to slow breakdown and possible accumulation

Disposal Considerations

Waste Treatment Methods: Incinerate with approved equipment, or dispose of as hazardous waste following local, national, and international regulations
Contaminated Packaging: Dispose of empty containers as hazardous waste, do not reuse for food or drink
Precautions for Disposal: Do not allow product to reach sewage system or open water; consult waste disposal specialists for incineration or secure landfill

Transport Information

UN Number: Not classified under UN regulations for transport
Proper Shipping Name: Not regulated for land, sea, or air transport in most countries
Hazard Class: Not assigned
Packing Group: Not assigned
Environmental Hazards: Not classified as marine pollutant, but safety measures call for preventing spills into waterways
Special Transport Precautions: Secure all containers to avoid tipping or leaks; shield from high temperatures and physical impacts

Regulatory Information

OSHA: Not specifically listed
TSCA: Listed in US Toxic Substances Control Act Inventory
EINECS/ELINCS: Listed in European Chemical Inventory
SARA Title III Section 313: Not subject to reporting
REACH Status: Registered or pre-registered for manufacturing or use in the EU
WHMIS (Canada): Not classified as controlled product
Other National Regulations: Users must comply with applicable national or regional health, safety, and environmental regulations
Labeling Requirements: Label containers with product name, hazard pictograms, precautions, and emergency contact details