Histry Chem

Knowledge

MSDS (Material Safety Data Sheet) for 1,5-Dichloropentane

Identification

Chemical Name: 1,5-Dichloropentane
Synonyms: Pentamethylene dichloride, Pentamethylene chloride
CAS Number: 111-18-2
Recommended Use: Used in organic synthesis and as an intermediate for pharmaceuticals and other specialty chemicals.
Manufacturer: [Company information provided by supplier]
Contact for SDS: [Emergency supplier phone, address, and email]

Hazard Identification

Classification: Flammable liquid, Harmful if inhaled or ingested, Causes skin and serious eye irritation
Signal Word: Warning
Hazard Statements: May cause damage to organs through prolonged or repeated exposure, Flammable liquid and vapor, Toxic to aquatic life, May cause respiratory tract irritation
Precautionary Statements: Wear protective gloves and eye protection, Keep away from ignition sources, Place containers upright and secure, Use only outdoors or in well-ventilated area, Avoid release into the environment

Composition / Information on Ingredients

Chemical: 1,5-Dichloropentane
Concentration: 98-100%
CAS Number: 111-18-2
Other Components: Trace impurities by-products and stabilized agents below reportable thresholds

First Aid Measures

Inhalation: Remove affected person to fresh air, support breathing, seek immediate medical attention if symptoms develop
Skin Contact: Immediately flush skin with plenty of running water, remove contaminated clothing, gently wash with soap and water, get medical attention for persistent irritation
Eye Contact: Flush eyes thoroughly with water for at least 15 minutes, keeping eyelids open, seek medical assessment for continued discomfort
Ingestion: Do not induce vomiting, rinse mouth, drink water only if fully conscious, call physician or poison control immediately

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, foam, carbon dioxide, water spray
Specific Hazards: May produce toxic gases including hydrogen chloride, carbon monoxide, phosgene on thermal decomposition
Special Protective Equipment: Self-contained breathing apparatus, full protective gear
Firefighting Advice: Remove containers from fire area if possible, cool surrounding containers with water spray, avoid direct stream on product to prevent spreading

Accidental Release Measures

Personal Precautions: Evacuate area, ventilate locality, use personal protective equipment as required, avoid skin and eye contact
Environmental Precautions: Prevent entry into drains, sewers, or waterways, report uncontrolled releases to authorities
Methods for Clean-Up: Absorb spillage with inert material (sand, earth, vermiculite), transfer to suitable waste containers, wash spill area with plenty of water, dispose of in accordance with local regulations

Handling and Storage

Safe Handling: Use only in areas with proper ventilation, minimize vapor generation, wear protective equipment, avoid contact with eyes and skin, prevent inhalation of vapor or mists
Storage: Keep container tightly closed in a dry, cool, well-ventilated location, keep away from heat, sparks, open flame, store away from oxidizers and strong acids, keep out of reach of children

Exposure Controls and Personal Protection

Occupational Exposure Limits: Consult national standards for guidance, limit exposure as low as reasonably achievable
Engineering Controls: Use explosion-proof ventilation and closed process systems, install emergency eyewash and deluge shower near worksite
Personal Protection: Chemical-resistant gloves, safety glasses with side shields, flame-retardant lab coat, suitable respiratory protection where vapor concentrations exceed exposure limits

Physical and Chemical Properties

Appearance: Clear, colorless to pale yellow liquid
Odor: Mild, ether-like odor
Odor Threshold: Not established
pH: Not applicable
Melting Point/Freezing Point: -64°C
Boiling Point/Range: 179–181°C
Flash Point: 63°C (closed cup)
Evaporation Rate: Not available
Flammability: Liquid and vapor
Explosive Limits: Lower: 2.0%, Upper: 10.9% (estimated)
Vapor Pressure: 1.5 mmHg at 25°C
Vapor Density: 5.1 (air = 1)
Relative Density: 1.114 at 20°C
Solubility: Insoluble in water; soluble in organic solvents
Partition coefficient (n-octanol/water): Log Kow 3.2
Auto-ignition temperature: 244°C
Decomposition Temperature: Not determined
Viscosity: Not determined

Stability and Reactivity

Chemical Stability: Stable under recommended handling and storage conditions
Reactivity: Reacts with strong oxidizing agents, strong bases, alkali metals
Hazardous Decomposition Products: Emits hydrogen chloride, carbon monoxide, carbon dioxide, phosgene if decomposed by fire
Conditions to Avoid: Elevated temperatures, open flame, sources of ignition
Polymerization: Not expected under normal conditions

Toxicological Information

Routes of Exposure: Inhalation, skin and eye contact, ingestion
Acute Toxicity (Oral): LD50 (rat): 1,800 mg/kg
Acute Toxicity (Dermal): Data not available, moderate irritation observed
Inhalation: Irritation to upper respiratory tract and mucous membranes
Skin Corrosion/Irritation: Causes moderate irritation
Eye Damage/Irritation: Causes severe irritation
Carcinogenicity: No data indicating carcinogenicity under current regulatory definitions
Mutagenicity: No available information
Reproductive Toxicity: Insufficient data
Other Hazards: Prolonged exposure can damage central nervous system, symptoms include drowsiness, headaches, or dizziness

Ecological Information

Toxicity to Aquatic Life: Toxic in high concentrations to aquatic organisms, causes long lasting harmful effects
Persistence and Degradability: Poorly biodegradable, may persist under environmental conditions
Bioaccumulation Potential: Moderate potential, may accumulate in living organisms
Mobility in Soil: Low solubility in water, adsorbs to organic material, may pose risk of groundwater contamination
Other Adverse Effects: Limited direct data, avoid uncontrolled environmental release

Disposal Considerations

Disposal Methods: Dispose of in accordance with local, regional, and national regulations for hazardous chemical waste, use licensed waste disposal contractors
Packaging Disposal: Drain containers thoroughly before disposal, do not reuse emptied containers, physically puncture and send for chemical waste processing where permitted
Special Precautions: Do not allow waste to contaminate soil, waterways, or drains, incineration may be the preferred method in compliance with environmental guidelines

Transport Information

UN Number: UN1993
UN Proper Shipping Name: Flammable liquid, n.o.s. (1,5-Dichloropentane)
Transport Hazard Class: 3
Packing Group: III
Reportable Quantity (RQ): Not established for this substance
Marine Pollutant: Yes
Special Precautions for Transport: Secure containers upright, handle in compliance with applicable regulations, follow emergency response protocols for leaks

Regulatory Information

OSHA Status: Regulated under Hazard Communication Standard
TSCA Inventory: Listed
SARA Section 313: Not subject to reporting requirements
WHMIS Classification (Canada): Flammable Liquid, Moderate Health Hazard
EU Regulation: Subject to REACH provisions, listed in EINECS
Other Applicable Regulations: National and local chemical management regulations apply, check regional guidelines for use, transport, and disposal
Label Requirements: Include hazard pictograms, signal words, and hazard/prevention statements as required under current GHS/CLP legislation