Histry Chem

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Material Safety Data Sheet for 1,12-Dodecanediol (DCO)

Identification

Product Name: 1,12-Dodecanediol
Chemical Formula: C12H26O2
Other Names: Dodecane-1,12-diol, Dodecanediol-1,12
CAS Number: 5675-51-4
Recommended Use: Intermediate for polymers, lubricants, surfactants, plasticizers, and pharmaceuticals
Supplier Information: Manufacturer or distributor details included with shipment or requested directly
Emergency Contact: Refer to CHEMTREC or local emergency service numbers specific to region

Hazard Identification

Classification: Not classified as hazardous under GHS, but handling precautions still apply
Potential Hazards: May cause mild eye or skin irritation with prolonged contact; inhalation of dust could irritate respiratory system; ingestion unlikely but could cause gastrointestinal upset
Physical Hazards: Not flammable in solid form, may emit irritating fumes if decomposed in fire
Environmental Hazards: Low toxicity reported for water organisms but avoid uncontrolled release to prevent accumulation

Composition / Information on Ingredients

Chemical Name: 1,12-Dodecanediol
Chemical Formula: C12H26O2
Synonyms: Dodecane-1,12-diol
PURITY: ≥98%
Impurities: <2%, minor alcohol byproducts, residual solvents as per specification sheet
Additives: No intentional additives reported for standard grades

First Aid Measures

Inhalation: Move person to fresh air. Seek medical advice if symptoms like coughing or shortness of breath develop.
Skin Contact: Wash area thoroughly with soap and water. Remove contaminated clothing. Get medical attention for persistent irritation.
Eye Contact: Flush eyes with lukewarm water for at least 15 minutes. Remove contact lenses if safe to do so. See a doctor if redness or pain persists.
Ingestion: Rinse mouth. Do not induce vomiting. Call a physician if feeling unwell.

Fire-Fighting Measures

Suitable Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide for surrounding fire.
Hazards from Combustion: May emit carbon monoxide, carbon dioxide, and other irritating vapors under fire conditions.
Protective Equipment: Firefighters should use self-contained breathing apparatus with full protective gear.
Special Measures: Cool exposed containers with water spray to prevent rupture.

Accidental Release Measures

Personal Precautions: Wear safety glasses, gloves, and dust mask; avoid breathing dust or vapors.
Environmental Precautions: Prevent entry into waterways, soil, and drains.
Cleanup Methods: Sweep up gently to minimize dust. Collect in labeled container for disposal. Wash spill site after material pickup is complete.

Handling and Storage

Handling: Use with adequate ventilation. Avoid dust generation. Wear appropriate protective clothing.
Safe Storage: Store tightly closed in a cool, dry, and well-ventilated area away from strong oxidizers. Keep containers upright and clearly labeled.
Incompatible Materials: Avoid contact with strong acids, oxidizers, and bases.

Exposure Controls and Personal Protection

Exposure Limits: No established workplace exposure limits for this substance.
Engineering Controls: Use adequate local exhaust ventilation to maintain exposure below nuisance dust limits.
Personal Protective Equipment: Wear chemical-resistant gloves, safety goggles, dust mask, and protective clothing.
Hygiene Measures: Wash hands thoroughly after handling and before eating or smoking. Do not eat, drink, or smoke in work areas.

Physical and Chemical Properties

Appearance: White crystalline solid
Odor: Faint, mild odor
pH (in water): Neutral
Melting Point: 98–102 °C (208–216 °F)
Boiling Point: 334 °C (633 °F) at 1013 hPa
Flash Point: >165 °C (329 °F)
Solubility: Slightly soluble in water, soluble in most organic solvents
Density: 0.96–1.0 g/cm³ at 20 °C
Vapor Pressure: Negligible under ambient conditions
Partition Coefficient (log Pow): 2.3–3.0 (estimated)
Viscosity: Not determined for solid form
Auto-ignition Temperature: >250 °C

Stability and Reactivity

Chemical Stability: Stable at room temperature under recommended storage conditions
Reactivity: Does not undergo hazardous reactions under normal use
Conditions to Avoid: High heat, open flame, moisture, incompatible materials
Incompatible Materials: Strong oxidizing agents, strong acids, alkalis
Decomposition Products: Carbon monoxide, carbon dioxide, possibly other toxic fumes on combustion

Toxicological Information

Acute Toxicity: Low acute oral and dermal toxicity in mammals; estimated LD50 (rat/oral) >2000 mg/kg
Skin and Eye Irritation: May cause mild, transient irritation upon direct contact
Sensitization: Rarely reported; insufficient evidence in humans
Chronic Toxicity: No data suggesting long-term toxicity at workplace exposure levels
Carcinogenicity, Mutagenicity, Reproductive Toxicity: No classification as carcinogen or mutagen; not on NTP, IARC, or OSHA lists
Other Information: Prolonged dust exposure could aggravate pre-existing respiratory conditions

Ecological Information

Eco-toxicity: Low toxicity to aquatic life based on available data
Persistence and Degradability: Biodegradable under aerobic conditions
Bio-accumulation: Low to moderate potential expected (log Pow under 4)
Mobility in Soil: Expected to have some mobility in soil but binds moderately
Other Adverse Effects: No data suggesting long-term environmental harm from small releases; large spills should be contained to avoid accumulation

Disposal Considerations

Waste Treatment Methods: Collect and dispose of in accordance with federal, state, and local regulations
Contaminated Packaging: Empty containers can be recycled or disposed of at approved waste facilities
Product Disposal: Incinerate or landfill as hazardous or industrial waste if contaminated; do not discharge into drains or watercourses
Special Precautions: Consult local, regional, and national authorities for most current regulations

Transport Information

UN Number: Not regulated for transport under UN, IMDG, IATA as a hazardous material
Proper Shipping Name: 1,12-Dodecanediol
Transport Hazard Class: Not classified
Packing Group: Not assigned
Special Precautions: Ship in intact, properly labeled containers; keep away from strong oxidizers during transit
Environmental Hazards: No special environmental hazard under standard transport regulations

Regulatory Information

Inventory Status: Listed on TSCA (US), EINECS (EU), DSL (Canada), ENCS (Japan), and other major registries
Labeling Requirements: Standard chemical labeling, handle as industrial chemical
Regulatory Restrictions: Not specifically regulated for consumer uses but intended for industrial use only
Other Regulations: Compliant with REACH (EU) and other national safety requirements for registration and notification where required